Sunday, August 1, 2010

SN1 Mechanism

The SN1 reaction is a substitution reaction in organic chemistry. "SN" stands for nucleophilic substitution and the "1" represents the fact that the rate-determining step is unimolecular.

SN1 reactions take place in two steps (excluding any protonation or deprotonation). The rate determining step is the first step, so the rate of the overall reaction is essentially equal to that of carbocation formation and does not involve the attacking nucleophile.
Thus nucleophilicity is irrelevant and the overall reaction rate depends on the concentration of the reactant only.
rate = k[reactant]


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